Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes
نویسندگان
چکیده
منابع مشابه
Dinitrogen Binding and Cleavage by Multinuclear Iron Complexes
The iron-molybdenum cofactor of nitrogenase has unprecedented coordination chemistry, including a high-spin iron cluster called the iron-molybdenum cofactor (FeMoco). Thus, understanding the mechanism of nitrogenase challenges coordination chemists to understand the fundamental N2 chemistry of high-spin iron sites. This Account summarizes a series of studies in which we have synthesized a numbe...
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Of all properties of metal nucleobase complexes, formation of multinuclear species appears to be an outstanding feature. After a brief introduction into well known polymeric metal nucleobase complexes, three aspects recently Studied in our laboratory will be dealt with in more detail: (i) Heteronuclear complexes derived from trans-[(amine)(2)Pt(1-MeC)(2)](2+) (1-MeC=1-methylcytosine). They form...
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Understanding the coordination of dinitrogen to iron is important for understanding biological nitrogen fixation aswell as for designing synthetic systems that are capable of reducing N2 to NH3 undermild conditions. This review discusses recent advances in iron–dinitrogen coordination complexes and describes the factors that contribute to the degree of activation of the coordinatedN2. The react...
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ژورنال
عنوان ژورنال: Accounts of Chemical Research
سال: 2015
ISSN: 0001-4842,1520-4898
DOI: 10.1021/acs.accounts.5b00213